Vol. 5, No. 4, April 2024
E-ISSN: 2723-6692
P-ISSN: 2723-6595
http://jiss.publikasiindonesia.id/
Jurnal Indonesia Sosial Sains, Vol. 5, No.4, April 2024 773
Silica Filter Membrane by Utilizing Palm Oil Empty Bunches
Waste
Reco Rambang Putra Negsagis, Hari Firmansah, Ultra Marsedi
PLN Sumatera Selatan, Indonesia
Email: reco.rambang@plnindonesiapower.co.id, hari.firmansah@plnindonesiapower.co.id,
ultra.marsedi@plnindonesiapower.co.id
Correspondence: eco.rambang@plnindonesiapower.co.id
KEYWORDS
ABSTRACT
Silica; Palm Oil Blank
Mark; Water Manager;
Fouling
Keramasan Gas and Steam Power Plant uses river water as
raw material after going through treatment in the WTP
system. To overcome the problem of high silica value in demin
water, a ceramic filter membrane device was developed from
empty palm oil bunch waste that reduced silica content to
standards. This research aims to improve water treatment
efficiency to meet the established water quality standards.
Keramasan Gas and Steam Power Plant uses river water
sources as raw materials, which are processed through the
WTP (Water Treatment Plant) system to produce
demineralized water as the main supply in the HRSG water
filler system. However, the water treatment process has not
been optimal because the silica content in demin water is still
high (>20 PPB), violating the established quality standards
(<20 PPB). Therefore, this study proposes an innovation in the
form of a ceramic filter membrane from empty palm oil bunch
waste to reduce silica content. Tests show a decrease in silica
values to standard. These innovations have had a positive
impact, including chemical savings, water treatment
optimisation, and wastewater reduction. In addition, the use
of empty palm oil waste also contributes to efforts to reduce
environmental pollution.
Attribution-ShareAlike 4.0 International (CC BY-SA 4.0)
1. Introduction
Keramasan Gas and Steam Power Plant (PLTGU Keramasan) which has a power of 2 x 40 MW
plays a very important role in supplying electricity needs, especially in the Southern Sumatra region
(Adam, 2016; B. N. Adha, 2018). The main water source used by PLTGU Keramasan comes from river
water which was previously treated first in the water treatment plant (WTP) system (Andhika, 2021;
Pratiwi et al., 2022). The process of processing river water into demin water must be optimal so that
the quality of the water produced is in good and normal conditions in accordance with standard
e-ISSN: 2723-6692 🕮 p-ISSN: 2723-6595
Jurnal Indonesia Sosial Sains, Vol. 5, No.4, April 2024 774
values and free from harmful substances. The dissolved content in water includes, silica, calcium
carbonate, free CO2, magnesium hydroxide, magnesium phosphate, iron oxide and so on. Silica is one
of the elements that can be harmful to industrial equipment, the presence of silica can cause scale or
deposits on tubes in HRSG and can cause damage to plant equipment (N. B. Adha, 2018; Andriani,
2004; Pratiwi, 2022).
The process of treating river water into demin water as HRSG (Heat Recovery Steam Generator)
filler water is still not optimal because the value of silica in water content is still fluctuating or tends
to be high below the standard value (> 20 PPB) which is influenced by various things (Sabar, 2023).
To avoid this, efforts need to be made to improve the quality of demin water to match the
predetermined standard value, which is < 20 PPB. Therefore, we had the idea to create a tool that can
help to accelerate the lowering of silica values according to standard values by utilizing empty palm
oil bunch waste. The tool is named "Silica filter membrane to accelerate the lowering of silica by
utilizing empty palm oil bunch waste". This membrane technology can reduce organic and inorganic
compounds in water content without the use of chemicals in its operation and as an effort to reduce
waste pollution of empty oil palm bunches (Abdulsalam et al., 2018; Aprilia & Amin, 2011).
From the above problems, the objectives of this innovation are as follows: Helps reduce the
silica content of water according to < 20 PPB standards; Optimize demin water treatment; Save on
the use of chemicals; Avoid water drain due to high silica value; Avoid equipment damage caused by
high silica values in water; Strive to reduce waste pollution.
2. Materials and Methods
The author uses a structured methodology in the preparation of this paper. First, local
observations and surveys were carried out on demin water treatment systems in Steam and Gas
Power Plants to identify problems on which the equipment development was based. Furthermore,
the improvement idea was designed to focus on reducing silica content in water. The manufacture of
tools is carried out by paying attention to the planned design and using materials that are easily
available. The next stage is repeated testing of the device to ensure its effectiveness in lowering the
value of silica in water. Finally, the report is prepared by compiling five chapters that include
introduction, theoretical foundation, discussion, benefits of tools and risk analysis, as well as
conclusions and suggestions. With this methodological approach, the authors succeeded in
developing a tool that has the potential to overcome water quality problems related to silica content.
3. Result and Discussion
Innovation Discussion
1. Identify the Problem
According to testing data on the results of demin water production in 2022 in figure 1, it shows
that the value of silica in water content is still fluctuating or tends to be high below the standard
value (> 20 PPB), resulting in several losses, including:
a) Demin water plant system is less than optimal (regeneration failure)
b) Waste of chemical injection during the treatment process to degrade silica
c) Waste of water for demin water production process
d) Loss of opportunity in demin water production
e) The potential for equipment damage due to silica content in water is still high
e-ISSN: 2723-6692 🕮 p-ISSN: 2723-6595
Jurnal Indonesia Sosial Sains, Vol. 5, No.4, April 2024 775
Figure 1 Data on the value of silica content in demin water Steam Gas Power Plant Shampooing
2. Problem Solving Analysis Based on the above problems, a problem-solving analysis was carried
out by making RCPS related to reducing the value of silica content in water in accordance with
the standard value as shown in figure 2 below.
Figure 2 Diagram RCPS
Based on the process of identifying problems through the diagnostic stage with the help of
tools such as RCPS diagrams, priority scale matrices and idea generation overview as well as
problem impact analysis, the author has several initiatives to make improvements so that this
problem can be resolved properly and does not cause losses to PLTGU Keramasan. The
improvement initiative offered by the author is a simple solution so that it can be implemented
immediately and immediately feel the benefits in the power unit. The improvement initiative or
breakthrough that has been made by the author is to make a silica filter membrane tool to reduce
silica content by utilising empty palm oil bunch waste (Anisah, 2015; Oyekanmi et al., 2021). The
selection of alternative improvements mentioned above is through several considerations, such
as determining the level of difficulty of implementation and the impact caused through a priority
scale matrix, which is then compiled in an idea generation overview related to the decision of
improvement initiatives that can be implemented immediately as shown in figure 3 below.
e-ISSN: 2723-6692 🕮 p-ISSN: 2723-6595
Jurnal Indonesia Sosial Sains, Vol. 5, No.4, April 2024 776
Figure 3 MANFISKA implementation priority idea matrix
3. Design of Innovation Works
A MANFISKA filter membrane can be made by composing it as specified in Figure 4 below.
Figure 4 The composition of the filter membrane material MANFISK
The tools and materials used to make this innovation, among other things:
Table 1 Tools and materials for making MANFISKA tools
No
Material
Total
1
Empty bunches of oil palm
15 gr
2
Clay
62,5 gr
3
Zeolite
20 gr
4
Iron powder
2,5 gr
5
Filter spon
3 unit
6
PVC Pipe
4 m
7
Measuring cup
1 Piece
8
Scales
1 Piece
The tools and materials provided are made cylindrical by membrane printing and sintering
(Kesting, 2006; Qian et al., 2022). The membrane is made from clay, empty oil palm bunches
e-ISSN: 2723-6692 🕮 p-ISSN: 2723-6595
Jurnal Indonesia Sosial Sains, Vol. 5, No.4, April 2024 777
(EFB), zeolite and iron filings moulded using a cylindrical mould of stainless steel and compacted
for 15 minutes (Sandra et al., 2014). This treatment is necessary so that the pressure applied can
be evenly distributed on the membrane. The resulting membrane measures 25 cm in length, 7
cm in outer diameter and 5 cm in diameter.
Figure 5 Printed membrane results
1) Principles of Tool Work
Water from the raw water tank is pumped to flow to the train cation, anions and mixed beds
to remove the mineral content, if the value of silica content in the water is still high > 20 PPB,
the water will flow to the silica filter membrane which serves to help reduce the silica value
to < 20 PPB. First, it passes through the housing-1 component which contains a sponge filter
with a pore diameter of 0.5 μm, then flows into housing-2 and housing-3 in which each
includes a sponge filter with a pore diameter of 0.1 μm and activated carbon, finally the
water passes through housing-4 which contains a ceramic membrane TKKS (empty oil palm
bunches) then the water is accommodated into the demin water tank (Sari et al., 2012).
Figure 6 MANFISKA tool components
e-ISSN: 2723-6692 🕮 p-ISSN: 2723-6595
Jurnal Indonesia Sosial Sains, Vol. 5, No.4, April 2024 778
4. Implementation
After assembling a membrane device made from TKKS (empty oil palm bunches), testing
was carried out to observe the performance of the tool in reducing the value of silica content in
water. The test results can be seen in figure 7 below :
Figure 7 Decrease in silica value after using MANFISKA
From the picture above, it can be seen that the MANFISKA membrane tool has been proven
in decreasing silica (Si) in water caused by the phenomenon of concentration polarization,
namely the blockage of membrane pores by silica (Si) where the concentration of silica (Si) on
the membrane surface is more concentrated than the concentration of silica (Si) passing through
the membrane.
5. Evaluation of Implementation Results
The implementation of MANFISKA has had a good impact on the generating unit, especially at
PLTGU Keramasan, where the silica value content of filler water can be maintained according to
< 20 PPB standards so that it can avoid the silica content contained in the filler water which has
an impact on the scale of the Keramasan PLTGU steam turbine.
Benefits of Innovation to Corporations
1. Benefits of innovation to corporate
a. Financial Benefits
Financial benefits obtained by calculating chemical losses due to regeneration failure due to
high silica content:
1) Potential regeneration failure 1 time for 3 hours:
Known:
NaOH price: IDR 12.000/kg
HCL price: IDR 5450/kg
NaOH requirement for 1 regeneration = 80 kg x IDR12,000 = IDR 1,080,000
e-ISSN: 2723-6692 🕮 p-ISSN: 2723-6595
Jurnal Indonesia Sosial Sains, Vol. 5, No.4, April 2024 779
kebutuhan HCL untuk 1 kali regenerasi = 160 kg x IDR 5,450 = IDR 872,000
Total chemical losses = IDR 1,080,000 + IDR 872,000
= IDR 1,952,000
2) Cost of manufacturing MANFISKA membranes :
Clay price: IDR 1000/kg
Zeolite price : IDR 1500/kg
Membrane printing price: IDR 75,000
PVC pipe price 4 meters: IDR 74,400
- Clay composition = 0,0625 kg x IDR 1000/kg = IDR 62.5
- The composition of zeolite = 0,020 kg x Rp 1500/kg = Rp 30
The total manufacture of MANFISKA tools is :
= IDR 75,000 + IDR 74,400 + IDR 62.5 + IDR 30
= IDR 149,492
3) The total savings obtained by using MANFISKA to help reduce silica are:
= IDR 1,952,000 - IDR 149,492 = IDR 1,802,508 / 1 regeneration failure
If in 1 month there are about 9 times failed regen due to the high value of silica, it is IDR
16,222,572 / month or Rp 194,670,864 / year.
b. Non-Financial Benefits
The non-financial benefits obtained from this innovation are as follows:
a) Helps in devaluing silica content.
b) Optimizing the demin water treatment system
c) Avoid water waste (drain) during the water treatment process
d) In an effort to reduce waste pollution.
e-ISSN: 2723-6692 🕮 p-ISSN: 2723-6595
Jurnal Indonesia Sosial Sains, Vol. 5, No.4, April 2024 780
c. Risk Analysis
After a risk assessment of the implementation of this innovation, several possible risks that occur
and their mitigation are obtained, as shown in the table below.
Table 2 Risk Table
4. Conclusion
The use of MANFISKA tools has been proven effective in reducing the value of silica content in
water, resulting in savings in the use of chemicals and increasing the optimality of demin water
treatment systems. In addition, utilising empty palm oil bunch waste as raw material for this tool
shows the potential for environmentally friendly solutions to water quality problems. For researchers
interested in researching the same variables, it is advisable to pay attention to the technical aspects
in the development of the tool, conduct more extensive trials to ensure the effectiveness of the tool,
as well as consider the environmental and economic implications of using this tool in the long term.
Thus, this study confirms that MANFISKA is a potential solution to overcome water quality problems
related to silica content, with significant benefits in chemical savings and waste utilisation.
5. References
Abdulsalam, M., Che Man, H., Isma Idris, A., Faezah Yunos, K., & Zainal Abidin, Z. (2018). Treatment of
Palm Oil Mill Effluent Using Membrane Bioreactor: Novel Processes and Their Major Drawbacks.
Water, 10(9), 1165. https://doi.org/10.3390/w10091165
Adam, L. (2016). Dinamika Sektor Kelistrikan Di Indonesia: Kebutuhan Dan Performa Penyediaan.
Jurnal Ekonomi Dan Pembangunan, 24(1), 29–41.
Adha, B. N. (2018). Analisis Prakiraan Kebutuhan Energi Listrik di PT. PLN (Persero)WS2JB Area
Palembang dengan Menggunakan Metode Exlanatory [Skripsi thesis, Universitas Negeri Jakarta].
http://repository.unj.ac.id/id/eprint/226
Adha, N. B. (2018). Analisis Prakiraan Kebutuhan Energi Listrik di PT. PLN (Persero) WS2JB Area
Palembang dengan Menggunakan Metode Exlanatory [Doctoral dissertation, Universitas Negeri
Jakarta]. http://repository.unj.ac.id/id/eprint/226
e-ISSN: 2723-6692 🕮 p-ISSN: 2723-6595
Jurnal Indonesia Sosial Sains, Vol. 5, No.4, April 2024 781
Andhika, Y. W. (2021). Perhitungan Energi Listrik Pemakaian Sendiri (Trafo PS) UNIT 1 dan 2 di PLTU
Baturaja [Undergraduate Theses, Politeknik Negeri Sriwijaya].
http://eprints.polsri.ac.id/id/eprint/11643
Andriani, Y. (2004). Pemakaian Membran Polisulfon Untuk Pemisahan Gas Hidrogen dan Karbon
Monoksida [ Thesis]. Universitas Indonesia.
Anisah, S. (2015). Pengaruh Annealling dan Stretching Terhadap Struktur Membran Hollow Fiber
Polipropilen [Thesis]. Institut Teknologi Bandung.
Aprilia, S., & Amin, A. (2011). Sintesis dan Karakterisasi Membran untuk Proses Ultrafiltrasi. Jurnal
Rekayasa Kimia Dan Lingkungan, 8(2), 84–88.
Kesting, R. E. (2006). Shynthetic Polymeric Membranes. McGrawHill Book Company.
Oyekanmi, A. A., Alshammari, M. B., Ibrahim, M. N. M., Hanafiah, M. M., Elnaggar, A. Y., Ahmad, A.,
Oyediran, A. T., Rosli, M. A., Mohd Setapar, S. H., Nik Daud, N. N., & Hussein, E. E. (2021). Highly
Effective Cow Bone Based Biocomposite for the Sequestration of Organic Pollutant Parameter
from Palm Oil Mill Effluent in a Fixed Bed Column Adsorption System. Polymers, 14(1), 86.
https://doi.org/10.3390/polym14010086
Pratiwi, I. (2022). Efektivitas Kulit Udang (Metapenaeus Monoceros) sebagai Biokoagulan pada Air
Sungai Kelekar menjadi Air Bersih (Studi Kasus: Air Sungai Kelekar sebagaiAir Bersih di Intake
Water Plant PLTGU Indralaya). Kinetika, 13(1), 1–11.
Pratiwi, I., Kurniasari, D., & Azaliyah, S. (2022). Efektivitas Kulit Udang (Metapenaeus Monoceros)
sebagai Biokoagulan pada Air Sungai Kelekar menjadi Air Bersih (Studi kasus: Air Sungai
Kelekar sebagai air Bersih di Intake Water Plant PLTGU Indralaya). Kinetika, 13(1), 1–11.
Qian, X., Ostwal, M., Asatekin, A., Geise, G. M., Smith, Z. P., Phillip, W. A., Lively, R. P., & McCutcheon, J.
R. (2022). A critical review and commentary on recent progress of additive manufacturing and
its impact on membrane technology. Journal of Membrane Science, 645, 120041.
https://doi.org/10.1016/j.memsci.2021.120041
Sabar, S. (2023). Pentingnya Pemeliharaan Nozzle untuk Mencegah Masalah pada Colling Tower
[Laporan Kerja Praktek]. Politeknik Negeri Bengkalis.
Sandra, K. O., Budi, A. S., & Susilo, A. B. (2014). Pengaruh Suhu Sintering Terhadap Densitas dan
Porositas pada Membran Keramik Berpori Berbasis Zeolit, Tanah Lempung, Arang Batok Kelapa,
dan Polivinylalcohol (PVA). Prosiding Pertemuan Ilmiah XXVIII HFI Jateng & DIY. Yogyakarta. Hal,
392–395.
Sari, E. P., Budo, A. S., & Budi, E. (2012). Pengaruh Aditif Arang Batok Kelapa Terhadap Densitas dan
Porositas Membran Keramik Berbasis Zeolit dan Tanah Lempung. Seminar Nasional Fisika 2012
Jakarta.